期刊
JOURNAL OF ENVIRONMENTAL MANAGEMENT
卷 108, 期 -, 页码 22-26出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2012.04.027
关键词
Biohydrogen; Sodium inhibition; Metabolic pathway; ATP; Dark fermentation
资金
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2009-0074155]
- Korea Ministry of Environment (MOE)
- National Research Foundation of Korea [2009-0074155] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Batch experiments were conducted to investigate the effects of Na+ concentration on hydrogen production with dark fermentation. The Na+ concentration was varied from 0 to 8 g/L in the mixed culture using an anaerobic sludge treated by acid. The maximum hydrogen production was achieved with 1 g-Na+/L, whereas the hydrogen production was decreased over 2 g-Na+/L due to the inhibitory of Na+. The mechanisms of Na+ inhibition to the hydrogen production are studied using pure culture of Clostridium butyricum by calculating the energy balance. At a high sodium concentration, C butyricum used a greater proportion of the ATP generated via fermentation for cell maintenance rather than for cell synthesis. Additionally, higher Na+ concentrations shifted the fermentation process toward the acetate synthesis pathway instead of the butyrate pathway, and the value of Y-X/ATP decreased. With high Na+ concentrations, a greater ratio of hydrogen was produced via the oxidation of NADH. Excess hydrogen production decreased as the Na+ concentration increased. (C) 2012 Elsevier Ltd. All rights reserved.
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