期刊
JOURNAL OF ELECTRONIC MATERIALS
卷 47, 期 12, 页码 7002-7010出版社
SPRINGER
DOI: 10.1007/s11664-018-6627-5
关键词
Ni0.85Se nanosheet; carbon fibers cloth; all-solid-state asymmetric supercapacitor; energy storage
资金
- National Natural Science Foundation of China [51671214, 51601210]
In this work, Ni0.85Se nanosheets array electrode material was prepared with carbon fiber cloth (CFC) as a substrate. Owing to their special structure, the Ni0.85Se nanosheets array exhibits an outstanding energy storage property with a superior specific capacitance (820F/g) and great rate capability (83.17%). Moreover, the Ni0.85Se electrode presents an great cycling performance with 82.63% retention after 10,000 cycles. The asymmetric supercapacitor (ASC) was fabricated based on Ni0.85Se positive and activated carbon (AC) negative electrode materials, with KOH/PVA gel as the electrolyte, respectively. A highest energy density of 29 Whkg(-1) was achieved at a power density of 779 Wkg(-1) under the optimal potential range of 1.6V. Furthermore, the Ni0.85Se//AC ASC devices demonstrate a great cycling performance of 81.25% capacitance retention after 5000 charge-discharge cycles. These excellent performance provide strong evidence to confirm the conclusion that Ni-0.85 Se nanosheets array used as electrode materials in supercapacitors and Ni-0.85 Se//AC asymmetric supercapacitors hold significant potential in the field of energy storage.
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