期刊
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
卷 185, 期 8-9, 页码 259-266出版社
ELSEVIER
DOI: 10.1016/j.elspec.2012.06.002
关键词
Ultrafast dissociation; Nuclear dynamics; Synchrotron radiation; High resolution photoelectron spectroscopy; Auger-Doppler
类别
Ultrafast dissociation following core-shell excitation into an antibonding orbital led to the early observation in HBr of atomic Auger lines associated to the decay of dissociated excited atoms. The purpose of this article is to review the very large variety of systems where such a situation has been encountered, extending from simple diatomic molecules toward more complex systems like polyatomics, clusters, or adsorbed molecules. Interestingly, this phenomenon has revealed an extremely rich and powerful tool for probing nuclear dynamics and its subtle interplay with electron relaxation occurring on a comparable time scale. Consequently this review covers a surprisingly large period, starting in 1986 and still ongoing. (C) 2012 Elsevier B.V. All rights reserved.
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