期刊
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
卷 177, 期 2-3, 页码 99-129出版社
ELSEVIER
DOI: 10.1016/j.elspec.2010.02.005
关键词
X-ray absorption spectroscopy; X-ray Raman scattering; Water; Ice
类别
资金
- National Science Foundation (US) [CHE-0809324, CHE-0431425]
- Swedish Research Council
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0809324] Funding Source: National Science Foundation
Here we present a review of X-ray absorption spectroscopy and X-ray Raman scattering with the perspective to understand the spectra of water including changes with temperature, mass of the water molecule and presence of monovalent ions. The different detection schemes are discussed and it is concluded that transmission X-ray absorption measurements, using a small area where the thickness is uniform, and X-ray Raman scattering give the most reliable spectra. Different model systems are discussed such as the surface and bulk of ice and various adsorbed monolayer structures on metal surfaces. Published by Elsevier B.V.
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