期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 720, 期 -, 页码 92-100出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2014.03.028
关键词
Cyclic voltammetry; Diffusion within a sphere; Templated porous electrodes; Potential step chronoamperometry
资金
- Engineering & Physical Sciences Research Council (EPSRC)
- St. John's College
- National Natural Science Foundation of China [20905035]
- Jiangsu Overseas Research & Training Program for University Prominent Young & Middle-aged Teachers and Presidents
- China Scholarship Council (CSC)
Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface. (C) 2014 Elsevier B.V. All rights reserved.
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