期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 646, 期 1-2, 页码 52-59出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2010.01.008
关键词
Cu(2)ZnSnS(4); Kesterite; Electrodeposition; Photovoltaics; Stacked elemental layer; Solar cells
资金
- TDK Corporation
- Fonds National de la Recherche Luxembourg (FNR)
- Engineering and Physical Sciences Research Council (EPSRC)
An improved electrodeposition-annealing route for preparing films of the Kesterite Cu(2)ZnSnS(4)(CZTS) for thin film solar cell absorber layers is demonstrated. The material is prepared by sequential electrodeposition of a metallic precursor stack in the order Cu/Sn/Cu/Zn and subsequent annealing of the stack in an atmosphere containing sulfur. The new precursor is demonstrably more uniform on both macro-and microscopic scales, and this translates to enhanced lateral uniformity of the photoresponse of the CZTS film. Photovoltaic devices were prepared from the films, with the best cell having an efficiency of 3.2%. (C) 2010 Elsevier B.V. All rights reserved.
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