期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 643, 期 1-2, 页码 77-81出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2010.03.006
关键词
Dopamine; Quantum dots; Zinc selenide; 3-Mercaptopropionic acid; Uric acid; Ascorbic acid
资金
- National Research Foundation (NRF), South Africa
Electrochemical detection of dopamine in the presence of excess ascorbic acid and uric acid on a gold electrode modified with 3-mercaptopropionic acid capped zinc selenide quantum dots is presented. The synthesized quantum dots were immobilized on the surface of gold disk electrode by self assembly method in dark conditions for 24 h and electrochemically characterized. A surface coverage of 0.91 was calculated using electrochemical impedance spectroscopy. The quantum dot afforded the simultaneous detection of these three compounds with wide peak separations which allowed the interferences to be masked with applied potential. Using a potential window of 0-400 mV, where only dopamine was electroactive, a detection limit of 2.43 x 10(-10) M and 5.65 x 10(-10) M were calculated from square wave voltammetry and amperometry respectively. (C) 2010 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据