期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 633, 期 1, 页码 1-6出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2009.04.013
关键词
Ordered mesoporous carbons; Soft template methods; Pore characteristics; Pt nanoparticles; Electrocatalytic activities
资金
- National Natural Science Foundation of China [50701023]
- Post-Doctoral Science Foundation of China [20060400283]
- Post-Doctoral Science Foundation of Jiangsu Province of China [2006277]
- Graduated Student Innovation Foundation of Jiangsu Province [CX07B_088z]
Two types of ordered mesoporous carbons (OMCs-FT and OMCs-F) with different hexagonal pore frameworks were synthesized via two soft template routes. Structural characterizations revealed that OMCs-FT possessed broader mesopore range, more enhanced mesoporosity and higher surface area, compared with the counterpart of OMCs-F. In order to systematically investigate the relationship between the pore characteristics and electrochemical performances, two catalysts of OMCs-FT/Pt and OMCs-F/Pt were achieved by ethylene glycol-assisted reduction procedure. X-ray diffraction (XRD) and transmission electron microscopy (TEM) measurements indicated that face-centered cubic Pt nanoparticles with an average size of 5.3 nm were homogeneously deposited on OMCs-FT while the mean size of 5.5 nm Pt nanoparticles had a relatively ransom dispersion on OMCs-F supports with some aggregations. The electrochemical results disclosed that OMCs-FT/Pt catalyst exhibited higher electrocatalytic activity and better stability than OMCs-F/Pt and commercially available E-TEK/Pt catalysts for methanol electro-oxidation. The broad mesopore range, enhanced mesoporosity and high surface area of OMCs-FT supports were considered to be the main reasons for its enhanced catalytic activity. (C) 2009 Published by Elsevier B.V.
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