期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 621, 期 2, 页码 129-133出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2007.07.026
关键词
TEMPO center dot; Reorganization energy; Standard rate constant; Transfer coefficient; Self-assembled monolayers
4-Amino-TEMPO center dot is attached to a self-assembled monolayers of HS(CH2)(10)COOH on gold electrodes and the kinetics of the TEMPO center dot/TEMPO+ redox couple are measured over a wide range of scan rates in 1 M H2SO4. Analysis of the rate constants yields the standard rate constant (1.2 s(-1)) and the reorganization energies for TEMPO center dot (1.5 eV) and TEMPO+ (1.3 eV). These values are the first experimental measurements of reorganization energies of TEMPO center dot in aqueous solution. 2007 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据