期刊
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
卷 33, 期 1-3, 页码 147-154出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/01932691.2010.548250
关键词
Adhesive properties; chain extender; phase separation; polyurethane dispersion
资金
- Institute for Small and Medium Industry of the Generalitat Valenciana (IMPIVA) [IMIDIC/2010/34]
Several waterborne polyurethane adhesives containing different chain extenders were prepared by using the acetone process. Concretely, the polyurethane dispersions were synthesized by the prepolymer method based on three chain extenders: two diols and one diamine: 1,4-butanediol, 1,6-hexanediol and hydrazine. The adhesive solutions were characterized by flow rheology, pH measurements, particle size, and solids content. The solid adhesive films were characterized by plate-plate rheology, dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). The adhesion properties were measured front T-peel test of leather/polyurethane adhesive/SBR rubber joints. As a result, the chosen chain extender influences significantly the polyurethane synthesized properties, especially determines the crystallinity of the polymer, as well as thermal and adhesive properties. Particularly, the molecular weight of the chain extender determines the structure of the synthesized polyurethanes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据