Radiolysis and sputtering of carbon dioxide ice induced by swift Ti, Ni, and Xe ions

Solid carbon dioxide (CO2) is found in several bodies of the solar system, the interstellar medium (ISM) and young stellar objects, where it is exposed to cosmic and stellar wind radiation. Here, the chemical and physical modifications induced by heavy ion irradiation of pure solid CO2 at low temperature (T = 15-30 K) are analyzed. The experiments were performed with Ti (550 MeV) and Xe (630 MeV) ions at the UNILAC of GSI/Darmstadt and with Ni ions (46 and 52 MeV) at IRRSUD of GANIL/Caen. The evolution of the thin CO2 ice films (deposited on a Csl window) was monitored by mid-infrared absorption spectroscopy (FTIR). The dissociation rate of CO2, determined from the fluence dependence of the IR absorption peak intensity, is found to be proportional to the electronic stopping power S-e. We also confirm that the sputtering yield shows a quadric increase with electronic stopping power. Furthermore, the production rates of daughter molecules such as CO, CO3 and O-3 were found to be linear in S-e. (C) 2015 Elsevier B.V. All rights reserved.