期刊
JOURNAL OF CRYSTAL GROWTH
卷 386, 期 -, 页码 204-207出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2013.10.001
关键词
Cu2ZnSn(SSe)(4) (CZTSSe); Quarternary alloys; Growth from melt
资金
- Japan Science Society
- Asahi Glass Foundation
- JSPS Research Fellowships for Young Scientists
I-2-R-IV-VI4 quaternary Cu2ZnSn(SxSe1-x)(4) (CZTSSe) alloys were successfully grown by the melting growth method. The powder X-ray diffraction (XRD) pattern of the CZTSSe alloys showed preferred orientations of (112), (220) and (312) planes, confirming the Kesterite structure. In Raman spectra, the A1 mode peaks expected for CZTS and CZTSe were observed in all samples, and no secondary phases were observed. The CZTSSe alloys in this study were slightly Cu-poor, Zn-rich and VI-rich, similar to compositions of polycrystalline thin-film materials that have achieved high photovoltaic conversion efficiencies. Single phase and homogeneous CZTSSe alloys were obtained. (C) 2013 Elsevier B.V. All rights reserved.
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