期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 66, 期 16, 页码 2821-2828出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2013.817571
关键词
Keggin-type polyoxometalates; Copper; Flexibility; Electrochemical property
资金
- National Natural Science Foundation of China [20971032, 21271056]
- Specialized Research Fund for the Doctoral Program of Higher Education [20122329110001]
- Natural Science Foundation of Heilongjiang Province [B201216]
- Program for Scientific and Technological Innovation Team Construction in Universities of Heilongjiang Province [2011TD010]
- Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education
A new compound, [{Cu-I(bim)}(4){SiW12O40}] (1) (bim=1,2-bis(imidazol-1-yl)ethane), was hydrothermally synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 is an infinite 1-D chain composed of Cu-bim coordination polymers and [-SiW12O40](4-) polyanions. The electrochemical and electrocatalytic behaviors of 1-modified carbon paste electrode (1-CPE) have been studied.
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