4.3 Article

Assembly of a new Keggin polyoxometalate-templated complex using flexible 1,2-bis(imidazol-1′-yl)ethane ligand

期刊

JOURNAL OF COORDINATION CHEMISTRY
卷 66, 期 16, 页码 2821-2828

出版社

TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2013.817571

关键词

Keggin-type polyoxometalates; Copper; Flexibility; Electrochemical property

资金

  1. National Natural Science Foundation of China [20971032, 21271056]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20122329110001]
  3. Natural Science Foundation of Heilongjiang Province [B201216]
  4. Program for Scientific and Technological Innovation Team Construction in Universities of Heilongjiang Province [2011TD010]
  5. Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education

向作者/读者索取更多资源

A new compound, [{Cu-I(bim)}(4){SiW12O40}] (1) (bim=1,2-bis(imidazol-1-yl)ethane), was hydrothermally synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 is an infinite 1-D chain composed of Cu-bim coordination polymers and [-SiW12O40](4-) polyanions. The electrochemical and electrocatalytic behaviors of 1-modified carbon paste electrode (1-CPE) have been studied.

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