期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 65, 期 22, 页码 4013-4022出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2012.731049
关键词
Hydrazone; Molybdenum complex; Crystal structure; Hydrogen-bonding; Sulfoxidation
资金
- Jingchu University of Technology
Two new dioxomolybdenum(VI) complexes, [MoO2L1(CH3OH)] (1) and [MoO2L2(H2O)] (2), where L-1 and L-2 are dianionic form of N'-(2-hydroxy-3-methoxybenzylidene)-4methoxybenzohydrazide and N'-(2-hydroxy-3methoxybenzylidene)-2-hydroxybenzohydrazide, respectively, have been synthesized and structurally characterized by spectroscopic methods and single-crystal X-ray determination. The complexes are mononuclear molybdenum(VI) compounds. Mo in each complex is octahedral. The difference in the substituent groups in the benzohydrazides leads to coordination of different solvent molecules. Crystals of the complexes are stabilized by hydrogen bonds. The complexes are effective catalysts for sulfoxidation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据