期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 64, 期 14, 页码 2554-2564出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2011.602071
关键词
Coordination polymer; Imidazole dicarboxylate; Crystal structure; Properties
资金
- National Natural Science Foundation of China [21071127, 20501017, J0830412]
- Program for New Century Excellent Talents in University
- Natural Science Foundation of Henan Education Department [2009A150028, 2011A150029]
Two polymeric frameworks, [Zn(5)(MIDC)(2)(HMIDC)(2)(phen)(5)](n) (1) (H (3)MIDC = 2-methyl-1H-imidazole-4,5-dicarboxylic acid, phen 1,10-phenanthroline) and {[Ca(2)(HEIDC)(2) (H(2)O)] center dot H(2)O}(n) (2) (H(3)EIDC = 2-ethyl-1H-imidazole-4,5-dicarboxylic acid), have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 3-D structure constructed from 2-D layer motifs joined by mu(2)-HMIDC(2-) or mu(3)-MIDC(3-) ligands. Compound 2 also presents a 3-D framework, generated from 1-D chains linked by HEIDC(2-) ligands by two different mu(5)-modes. The thermal and solid-state photoluminescence properties of both the complexes have been determined.
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