期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 62, 期 17, 页码 2860-2868出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970902946702
关键词
Schiff base; Copper; Zinc; Crystal structure; Urease inhibitory property
资金
- Natural Science Foundation of China [30771696]
- Natural Science Foundation of Zhejiang Province [Y407318]
- Science and Technology Plan of Huzhou [2008YS16]
A new copper(II) complex, [CuL(1,1-N3)]n (1), and a new zinc(II) complex, [ZnL(2-acetato-O, O')2]n (2) (HL = 2-bromo-4-chloro-6-[(2-dimethylaminoethylimino)methyl]phenol), were prepared and characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Complex 1 is an end-on azide-bridged polynuclear copper(II) complex and 2 is a syn-anti bidentate acetate-bridged polynuclear zinc(II) complex. Each metal in the complex is five-coordinate with square-pyramidal geometry. Complex 1 shows good urease inhibitory properties, while 2 does not.
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