期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 62, 期 2, 页码 151-204出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970802398178
关键词
Schiff bases; Mononuclear complexes; Di- and oligodentate azomethine ligands with N; C-; N; N-; N; P-; N; O-; N; S-; N; Se-; N; Te-donor centers; C-; N-; O-; S-; Se-; Te- Salen chelates; Standard and nonstandard structures
资金
- Ministry of Education and Science of Russian Federation [RNP.2.1.1.1875]
- RFBR [08-03-00154, 07-03-00256, 08-08-00223]
- Internal grant of Southern Federal University [05/6-129]
- RF President [NS-353.2008.3]
- PAICyT-UANL projects, Monterrey-Mexico [2007]
Data on molecular design of various types of mononuclear complexes of Schiff bases are generalized. Factors for variation of fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined. A systematization of Salen complexes is offered. Electronic configurations of p- and d-metals in the coordination and organometallic compounds are taken into account in a series of chelate structures. Non-standard structures are emphasized, including various ligand chelates and molecular complexes.
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