期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 61, 期 23, 页码 3869-3878出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970802178265
关键词
Morin; Molecular mechanics; Density functional theory; Paramagnetic shift
资金
- CSIR
Studies on nine-coordinate lanthanide complexes of morin are described. The complexes were characterized by elemental analysis, molar conductance, UV-Vis spectra, IR spectra, thermal analysis and NMR spectra. Molecular modeling studies were also carried out. The complexes are non-electrolytes in DMSO. TGA showed anhydrous nature of the complexes. The electronic spectra of the complexes were recorded in methanol. H-1 NMR spectra of lanthanum, praseodymium, neodymium, samarium and dysprosium complexes have been studied in DMSO-d(6). The complexes do not dissociate in DMSO and retain their coordination. H-1 NMR spectra of paramagnetic and diamagnetic complexes exhibit downfield as well as upfield shifts of morin resonances that shows change in geometry during coordination.
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