期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 532, 期 -, 页码 433-440出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.07.121
关键词
Amino acids; Porous hypercrosslinked polymers; Microspheres; High CO2 capturing capacity
资金
- National Natural Science Foundation of China [51503060]
- Hubei Nature Science Foundation of China [2014CFB549]
Advanced porous organic materials with high gas storage capacity and high selectivity have been rapidly developed for CO2 adsorbents in the recent decade, due to extremely high surface area and nanoscale pore size. Here, novel amino acids-incorporated solid adsorbents based on porous hypercrosslinked polymers were fabricated by a dispersion polymerization of an aromatic monomer and quaternary ammonium salt comonomer, subsequently a hypercrosslinked reaction and an ion-exchange step. The developed adsorbents presented mesopores structure with BET surface area up to 864 m(2)/g and an extremely high CO2 capturing capacity up to 60.7 wt% (13.8 mmol/g) at 273 K/1 bar. The results also showed the adsorbent had an excellent recycling ability over repetitive adsorption-desorption cycles. All the results suggest that the amino acids-modified porous sorbents are promising CO2 sorbents that can meet the challenges of the current CO2 capture and storage technology. (C) 2018 Elsevier Inc. All rights reserved.
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