期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 432, 期 -, 页码 86-91出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2014.06.011
关键词
Pd@SBA-15/En; Mizoroki-Heck reaction; Cross-coupling; Transition-metal complex
A series of Pd-complexes of amine and diamine ligands embedded into the ordered silica mesoporous (PdX2@SBA-15/N-Y, Y = 1, 2) are synthesized. Among them, the covalently bonded Pd(OAc)(2)/ethylenediamine complex into the SBA-15 exhibit higher activity and selectivity toward Mizoroki-Heck cross-coupling reaction. The Pd(OAc)(2)@SBA-15/En pre-catalyst could be separated easily from reaction products and used repetitively several times, showing the superiority over the homogeneous catalysts for industrial and chemical applications. (C) 2014 Elsevier Inc. All rights reserved.
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