期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 432, 期 -, 页码 207-213出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2014.06.050
关键词
Fe3O4 magnetic nanoparticles; Carbon nanotubes; Dopamine; Ascorbic acid; Uric acid
资金
- Fundacao para a Ciencia e a Tecnologia (FCT) [PEst-C/EQB/LA0006/2013, PTDC/CTM-POL/0813/2012]
- MICINN of Spain [CTQ-2011-29272-C04-01, CTQ-2011-29272-C04-03]
- FCT [SFRH/BPD/74877/2010]
- [NORTE-07-0124-FEDER-000067-Nanochemistry]
- Fundação para a Ciência e a Tecnologia [PTDC/CTM-POL/0813/2012] Funding Source: FCT
A new modified electrode based on N-doped carbon nanotubes functionalized with Fe3O4 nanoparticles (Fe3O4@CNT-N) has been prepared and applied on the simultaneous electrochemical determination of small biomolecules such as dopamine (DA), uric acid (UA) and ascorbic acid (AA) using voltammetric methods. The unique properties of CNT-N and Fe3O4 nanoparticles individually and the synergetic effect between them led to an improved electrocatalytic activity toward the oxidation of AA, DA and UA. The overlapping anodic peaks of these three biomolecules could be resolved from each other due to their lower oxidation potentials and enhanced oxidation currents when using the Fe3O4@CNT-N modified electrode. The linear response ranges for the square wave voltammetric determination of AA, DA and UA were 5-235, 2.5-65 and 2.5-85 mu mol dm(-3) with detection limit (S/N = 3) of 0.24, 0.050 and 0.047 mu mol dm(-3), respectively. These results show that Fe3O4@CNT-N nanocomposite is a promising candidate of cutting-edge electrode materials for electrocatalytic applications. (C) 2014 Elsevier Inc. All rights reserved.
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