期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 389, 期 -, 页码 199-205出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2012.09.032
关键词
Piperidinium salts; Lyotropic liquid crystal; Polarized optical microscopy; Small angle X-ray scattering
资金
- National Natural Science Foundation of China [20773080, 20973104, 21033005]
- National Science Foundation for Post-doctoral Scientists of China [2012M511555]
- Natural Science Fund of Shandong Province [2009ZRB01147]
The lyotropic liquid crystalline (LLC) phases formed by a series of N-alkyl-N-methylpiperidinium bromides (CnPDB, n = 12, 14, 16) in water have been investigated. By using polarized optical microscopy (POM) and small angle X-ray scattering (SAXS) techniques, the normal hexagonal (H-1) and reverse bicontinuous cubic (V-2) LLC phases can be detected with C14PDB/H2O and C16PDB/H2O systems within a large temperature and concentration ranges. In the C12PDB/H2O system, only the H-1 phase is observed. Such differences may be attributed to differences in hydrophobic interactions resulting from their different alkyl chain lengths. The theological results reveal that the H-1 phase formed by C12PDB displays a typical Maxwell behavior, whereas those with C14PDB or C16PDB show gel-like behavior, unlike the traditional cationic surfactants. The obtained results on the LLC phases formed by this new class of piperidinium surfactants supplement the current understanding about nitrogen-containing heterocyclic headgroup-based cationic surfactants and may open their wide potential applications. (C) 2012 Elsevier Inc. All rights reserved.
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