期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 398, 期 -, 页码 185-192出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2013.01.067
关键词
Mesoporous manganese ferrite microspheres; Anode materials; Electrochemical properties; Li-ion batteries
资金
- Hundred Talents Program of the Chinese Academy of Sciences (CAS)
- State Key Laboratory of Multiphase Complex Systems of China [MPCS-2011-D-14]
- National Natural Science Foundation of China [21031005, 51272252]
We report the synthesis and characterization of the mesoporous manganese ferrite (MnFe2O4) microspheres as anode materials for Li-ion batteries. MnFe2O4 microspheres were synthesized by a facile solvothermal method using Mn(CH3COO)(2) and FeCl3 as metal precursors in the presence of CH3COOK, CH3COOC2H5, and HOCH2CH2OH. The samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption, thermal gravimetric, X-ray photoelectron spectroscopy, temperature programmed reduction, and temperature programmed oxidation. The synthesized mesoporous MnFe2O4 microspheres composed of nanoparticles (10-30 nm) were 100-500 nm in diameter and had surface areas between 60.2 and 86.8 m(2) g(-1), depending on the CH3COOK amounts added in the preparation. After calcined at 600 degrees C, MnFe2O4 was decomposed to Mn2O3 and Fe2O3 mixture. The mesoporous MnFe2O4 microspheres calcined at 400 degrees C showed a capacity of 712.2 mA h g(-1) at 0.2 C and 552.2 mA h g(-1) at 0.8 C after 50 cycles, and an average capacity fading rate of around 0.28%/cycle and 0.48%/cycle, much better than those of the samples without calcination and calcined at 600 degrees C. The work would be helpful in the fabrication of binary metal oxide anode materials for Li-ion batteries. (C) 2013 Elsevier Inc. All rights reserved.
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