期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 377, 期 -, 页码 291-298出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2012.03.021
关键词
BiOCl; BiOBr; Rhodamine B; Photosensitized degradation; Methyl Orange; Methylene Blue
资金
- Natural Science Foundation of China [51172109]
- Natural Science Foundation of Jiangsu Province in China [BK2010497]
This study reported, for the first time systematically, photodegradation of Rhodamine B (RhB) in aqueous solution over BiOCl and BiOBr semiconductors. Under visible light irradiation (lambda > 400 nm, lambda > 420 nm and lambda = 550 +/- 15 nm), RhB adsorbed on the surface of BiOCl and BiOBr was photosensitized and decomposed effectively over unexcited BiOCl and BiOBr. The degradation of Methyl Orange (MO) and Methylene Blue (MB) over BiOCl and BiOBr was investigated as well, and the results were compared with RhB photodegradation. It was found that MB molecules having the lowest LUMO could not be degraded by this process. Utilizing the quantum chemical calculation (Gaussian 03 program), the relationship between frontier orbital energy of selected dye molecules and photodegradation rate was established for the first time in this study. Crown Copyright (C) 2012 Published by Elsevier Inc. All rights reserved.
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