期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 362, 期 2, 页码 325-329出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2011.07.010
关键词
Gold nanoparticles; Silver nanoparticles; Inorganic synthesis; Casein
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22710102]
- JST CREST
- Grants-in-Aid for Scientific Research [22710102] Funding Source: KAKEN
Gold nanoparticles were fabricated by reduction of highly concentrated Au(III) ions (200 mM) with casein proteins from milk. The gold nanoparticles were converted to nanoparticle-powders after washing and subsequent vacuum drying without aggregation. The nanoparticle-powders completely re-dispersed in aqueous solution, and stable colloidal gold nanoparticles were obtained. UV-vis extinction spectra and dynamic light scattering (DLS) measurements revealed that large assemblies (size, ca. 3 mu m) and subaggregates (size, <0.51 mu m) composed of gold nanoparticle-casein protein chain-Au(III) ion were dynamically formed and disintegrated over the course of the growth of the gold nanoparticles. Fourier transform infrared (FT-IR) spectra indicated conformational changes of casein proteins induced by the interaction of casein protein-Au(III) ion and -gold nanoparticle. Finally, rapid, one-pot, and highly concentrated synthetic procedures of gold and silver nanoparticle powders protected by casein (mean diameters below 10 nm) were successfully developed using 3-amino-1-propanol aqueous solutions as reaction media. Dense colloidal gold (40 g L-1) and silver (22 g L-1) nanoparticle aqueous solutions were obtained by re-dispersing the metal nanoparticle powders. (C) 2011 Elsevier Inc. All rights reserved.
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