期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 334, 期 1, 页码 29-36出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2009.03.010
关键词
Polyol; Synthesis; Transparent conductive oxides; Zinc oxide; Nanomaterial
资金
- European Union.
- Center for Functional Nanostructures (CFN) of the Deutsche Forschungsgemeinschaft (DFG) at the University of Karlsruhe (TH)
Microwave heating is applied to prepare suspensions of ZnO:In (IZO) and ZnO:Al (AZO) nanocrystals in diethylene glycol as a high-boiling multidentate alcohol (so-called polyol). Both n-doped zinc oxides are realized with high yields and in suspensions with solid contents up to 10 wt-%. These suspensions are colloidally stable for months. According to dynamic light scattering, scanning electron microscopy, transmission electron microscopy, X-ray diffraction patterns and Brunauer-Emmett-Teller analysis as prepared particles turn out to be single crystalline with an average diameter of 10-15 nm, a near monodisperse size distribution, and a low degree of agglomeration. As-prepared samples exhibit high resistivities due to the adhesion of DEG as a stabilizer on the particle surface. Subsequent to specific thermal post-treatment resistivities of 2.0 x 10(-1) and 5.7 x 10(-1) Omega cm are obtained for IZO and AZO powders, respectively. As a proof of the concept, thin layers are deposited on glass plates using a simple solvent evaporation technique. Post-treated layers exhibit a visible transmittance of about 80% and resistivities of 2.1 x 10(-1) Omega cm (IZO) and 2.6 x 10(-1) Omega cm (AZO). The bandgap of post-treated powders and thin layers is calculated to 3.2 and 3.3 eV, respectively. (c) 2009 Elsevier Inc. All rights reserved.
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