期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 334, 期 1, 页码 1-7出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2009.03.020
关键词
Metal organic framework (MOF); Clathrate; CO2 separation; CH4 storage
资金
- Fundamental Scientific Research (B) [19350100]
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [19350100] Funding Source: KAKEN
Elastic layer-structured metal organic frameworks (ELMS) having flexible two-dimensional structure show a gate phenomenon in sorption/desorption of simple gas molecules. The gate phenomenon is accompanied by expansion/shrinkage of the layers. The gas sorption/desorption is not based on a physical adsorption, but on a chemical reaction, which includes high cooperativity. The cooperative reaction could be analyzed thermodynamically. The gate phenomenon showed advantages in separation of CO2 from mixed gases and in storage of CH4 owing to easy release of absorbed molecules. (c) 2009 Elsevier Inc. All rights reserved.
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