期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 336, 期 2, 页码 654-657出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2009.04.081
关键词
Platinum-gold catalysts; Oxygen reduction reaction (ORR); Temperature-programmed reduction (TPR); Alloying
资金
- National Science Council of Taiwan [NSC-97-2221-E-008-042]
Alloy catalysts of Pt-Au/C with various Pt/Au ratios were prepared for an oxygen reduction reaction (ORR). The structure, Surface species, surface compositions, and electrocatalytic activities of prepared alloy catalysts were characterized by XRD, TPR, XPS, and rotating disk electrode (RDE) techniques. respectively. it was observed that the ORR activity of the Pt75Au25/C alloy catalyst was enhanced significantly in comparison to the commercial Pt/C catalyst within the mixed kinetic-diffusion control region. The alloying with Au modified the oxophilicity of Pt-Au alloy catalysts. TPR characterization suggests that the enhancement Of Pt75Au25/C was attributed to the formation of an alloy surface, having a moderate oxophilicity and a Pt-related alloy surface species. (C) 2009 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据