期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 327, 期 2, 页码 287-294出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2008.08.049
关键词
Montmorillonite; Organoclay; High resolution thermogravimetric analysis; X-ray diffraction; Transmission electron microscopy
资金
- Chinese Academy of Sciences [Kzcx2-yw-112]
- Natural Science Foundation of Guangdong Province [030471, 05103410]
- Queensland University of Technology
Organoclays were synthesized by the ion exchange of cationic surfactants containing single, double and triple alkyl chains for sodium ions in an aqueous suspension of Wyoming Na-montmorillonite. The characterization of organoclays with and without adsorbed phenol was determined by X-ray diffraction, TEM and thermal analysis. Differences in the surfaces and in the interlayer of the mono, di and tri alkyl chain organoclays resulted in differences in the adsorption efficiency for phenol with tri > di > mono >> Na-Mt. The results prove that organoclays can be effective for the removal of phenol from an aqueous solution and this removal is a function of the surfactant molecule and its concentration. In general, the higher the concentration as measured by the CEC value and the greater the number of alkyl chains in the surfactant molecule, the greater the percentage of the phenol that is removed. (C) 2008 Elsevier Inc. All rights reserved.
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