期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 6, 页码 4591-4600出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj02134g
关键词
-
资金
- Iran's National Elites Foundation
A novel heterogeneous copper catalyst based on poly(ionic liquid)-coated magnetic nanoparticles was prepared by the polymerization of 3-carboxymethyl-1-vinylimidazolium in the presence of surface-modified magnetic nanoparticles, followed by the coordination of the carboxylate units in the polymer chains with copper sulfate. The resulting catalyst has a high level of loading of copper ions and is used in low weight percent. The catalytic activity of the newly designed catalyst was tested in a one-pot synthesis of 1,4-disubstituted 1,2,3-triazoles by click reactions between primary halides or tosylates, sodium azide and terminal acetylenes at room temperature in aqueous media. The unique nanocatalyst structure and the multi-layered form of coated polymer on the magnetite surface are responsible for the excellent catalytic performance for click reactions.
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