期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 7, 页码 5529-5533出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj00889a
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资金
- Russian Science Foundation [14-23-00013]
- Russian Science Foundation [14-23-00013] Funding Source: Russian Science Foundation
Two new complexes based on 4,4'-ethylenepyridinium cations and binuclear Bi(III) anionic complexes, (H(2)bpe)(2)[Bi2X10]center dot 2H(2)O (bpe = 1,2-bis(4-pyridyl) ethane; X = Cl (1), Br (2)), have been synthesized and characterized by X-ray diffractometry. In both cases, loss of solvent H2O molecules affects the luminescence behavior, resulting in increase of intensity (ca. 5-fold). Desolvation is reversible, which is of potential use in chemosensor systems.
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