期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 5, 页码 3564-3570出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj02319f
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资金
- Ministry of Education Malaysia [RDU 140124]
SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100-500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki-Heck, Suzuki-Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and used five times without a significant loss of its catalytic activity.
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