期刊
NEW JOURNAL OF CHEMISTRY
卷 39, 期 1, 页码 142-154出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj01515k
关键词
-
资金
- DST [SR/S1/IC-73/2010]
- DRDO [NRB-213/MAT/10-11]
- UGC [36-21/2008 (SR)]
- CSIR [3732/NS-EMRII]
Five phenanthromidazole derivatives, namely 2-(naphthalen-1-yl)-1H-phenanthro[9,10-d]imidazole (1), 2-(naphthalen-1-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole (2), 2-(naphthalen-1-yl)-1-p-tolyl-1H-phenanthro[9,10-d]imidazole (3), 1-(4-methoxyphenyl)-2-(naphthalen-1-yl)-1H-phenanthro[9,10-d]imidazole (4) and 1-(3,5-dimethylphenyl)-2-(naphthalen-1-yl)-1H-phenanthro[9,10-d]imidazole (5), were synthesised using the TiO2 (R) nanosemiconductor as the catalyst under solvent free conditions and characterised by NMR and single crystal XRD techniques. Their photophysical, electrochemical and electroluminescent properties were carefully analysed. Highly efficient Alq(3)-based organic light emitting devices have been developed using phenanthromidazoles as functional layers between NPB [4,4-bis(N-(1-naphthyl)-N-phenylamino)biphenyl] and Alq(3) [tris(8-hydroxyquinoline)aluminium] layers. Using the device of ITO/NPB/4/Alq(3)/LiF/Al, a maximum luminous efficiency of 5.99 cd A(-1) was obtained with a maximum brightness of 40 623 cd m(-2) and a power efficiency of 5.25 lm W-1.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据