期刊
JOURNAL OF CLEANER PRODUCTION
卷 203, 期 -, 页码 685-695出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2018.08.231
关键词
Electro-Fenton process; Hydroxyl radical; Gas-diffusion-electrode cathode; Sacrificial iron anode
Hydroxyl radical (center dot OH) generation in the electro-Fenton process with in situ electro-chemical production of Fenton reagents, i.e. hydrogen peroxide and ferrous ion, by the gas-diffusion-electrode cathode and sacrificial iron anode was systematically investigated. Effects of solution pH and current density (J) on center dot OH generation linked strongly with electro-chemical production of hydrogen peroxide at the gas diffusion-electrode cathode and corrosive production of ferrous ion at sacrificial iron anode were examined. The optimal pH for center dot OH generation in the electro-Fenton process was 3 being optimal for the Fenton reaction. The center dot OH generation at pH 3 was enhanced with increasing current density and reached the maximum at J = 5.8mAcm(-2). Further increase in the current density resulted in the retardation of center dot OH generation rate. To quantify the center dot OH generation, a novel phenomenological reaction kinetic model was developed. The proposed model could quantitatively clarify the center dot OH generation in the electro-Fenton process with in situ electro-chemical production of Fenton reagents. (C) 2018 Elsevier Ltd. All rights reserved.
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