Analysis of risk trade-off relationships between organic solvents and aqueous agents: case study of metal cleaning processes

When substance substitution is implemented to reduce the target risk of production processes, countervailing risks may occur. The goal of this study is to analyze the risk trade-off relationships between organic solvents and aqueous agents in the case study of metal cleaning processes. Global environmental impacts and local risks were evaluated for the eight scenarios by life cycle and risk assessments, respectively. The results show that the contribution of the processes using chlorinated solvents to photochemical ozone creation, human toxicity, ozone depletion, and ecotoxicity was larger than processes using aqueous detergents, while the contribution of aqueous processes to eutrophication was larger than chlorinated processes. Neighbors' health risk around a cleaning site using chlorinated solvents was sufficiently small in all scenarios, whereas ecological risk due to surfactants which are contained in aqueous detergents and emitted to the local aquatic environment should be reduced. Cleansing agents and process facilities should be selected on the basis of the comprehensive analysis of risk trade-off relationships for feasible and cleaner production. (C) 2010 Elsevier Ltd. All rights reserved.