期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1217, 期 8, 页码 1244-1248出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2009.12.062
关键词
Ionic liquid; Dispersive liquid-liquid microextraction; Carbamate pesticides; Low-density extraction solvent; Gas chromatography-tandem mass spectrometry
资金
- National Natural Science Foundation of China [20705009]
- Research Fund for New Teachers of Higher Education of China [20070504039]
A simple and fast method of low-density extraction solvent-based solvent terminated dispersive liquid-liquid microextraction (ST-DLLME) was developed for the highly sensitive determination of carbamate pesticides in the water samples by gas chromatography-tandem mass spectrometry (GC-MSMS) After dispersing, the obtained emulsion cleared into two phases quickly whets an aliquot of acetonitrile was Introduced as a chemical demulsifier into the aqueous bulk Therefore, the developed procedure does not need centrifugation to achieve phase separation. It was convenient for the usage of low-density extraction solvents in DLLME Under the optimized conditions, the limits of detection for all target carbamate pesticides were in range of 0 001-0 50 ng mL(-1) and the precisions were in the range of 23-6 8% (RSDs. 2 ng mL(-1), n=5) The proposed method has been successfully applied to the analysis of real water samples and good spiked recoveries over the range of 94 5-104% were obtained. (C) 2009 Elsevier B V All rights reserved
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