4.5 Article

Recommended sublimation pressure and enthalpy of benzene

期刊

JOURNAL OF CHEMICAL THERMODYNAMICS
卷 68, 期 -, 页码 40-47

出版社

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2013.08.022

关键词

Benzene Vapor pressure; Heat capacity; Ideal-gas thermodynamic properties; Sublimation enthalpy; Recommended vapor pressure equation

资金

  1. MSMT [20/2013]

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Recommended vapor pressures of solid benzene (CAS Registry Number: 71-43-2) which are consistent with thermodynamically related crystalline and ideal-gas heat capacities as well as with properties of the liquid phase at the triple point temperature (vapor pressure, enthalpy of vaporization) were established. The recommended data were developed by a multi-property simultaneous correlation of vapor pressures and related thermal data. Vapor pressures measured in this work using the static method in the temperature range from 233 K to 260 K, covering pressure range from 99 Pa to 1230 Pa, were included in the simultaneous correlation. The enthalpy of sublimation was established with uncertainty significantly lower than the previously recommended values. (C) 2013 Elsevier Ltd. All rights reserved.

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