期刊
JOURNAL OF CHEMICAL THERMODYNAMICS
卷 57, 期 -, 页码 9-13出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2012.08.007
关键词
Tetracycline hydrochloride; Solubility; Modified Apelblat; NRTL; UNIQUAC
资金
- National Natural Science Foundation of China [20836005, 21176173]
The solubility of Tetracycline hydrochloride (TCH) in methanol, ethanol, 1-propanol, 1-butanol, acetone, and acetonitrile, was measured using a static method from (283.15 to 318.15) K. The solubility of TCH decreased in the order of methanol, ethanol, 1-propanol, 1-butanol, acetone, and acetonitrile. With increasing temperature, the solubility of TCH increased in ethanol, 1-propanol, 1-butanol, acetone, and acetonitrile but decreased in methanol. Moreover, the experimental solubility data were correlated by the modified Apelblat equation, NRTL and UNIQUAC models, respectively. And the calculated data by NRTL model showed better agreement with experimental values than the modified Apelblat equation and UNIQUAC model. (C) 2012 Elsevier Ltd. All rights reserved.
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