期刊
JOURNAL OF CHEMICAL THERMODYNAMICS
卷 40, 期 3, 页码 362-368出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2007.10.001
关键词
energy of combustion; enthalpy of vaporization; enthalpy of formation; rotating bomb combustion calorimetry; Cox scheme; chloroanisole isomers
The standard (p degrees = 0.1 MPa) molar enthalpies of formation, in the liquid phase, of 2-, 3- and 4-chloroanisoles, at T = 298.15 K, were derived from their standard massic energies of combustion, in oxygen, to yield CO2(g) and HC1 center dot 600H(2)O(l), measured by rotating bomb combustion calorimetry. The Calvet high-temperature microcalorimetry technique was used to measure the standard molar enthalpies of vaporization of these compounds. [GRAPHICS] From these two sets of experimental values, the standard molar enthalpies of formation in the gaseous phase, at T = 298.15 K, were derived, compared with the same parameters estimated by the Cox scheme and interpreted in terms of molecular structure. (c) 2007 Elsevier Ltd. All rights reserved.
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