Part 2:: Limiting apparent molar volume of organic and inorganic 1:1 electrolytes in (water plus ethylammonium nitrate) mixtures at 298 K -: Thermodynamic approach using Bahe-Varela pseudo-lattice theory

Values of partial molar volumes at infinite dilution of 9 inorganic and 4 organic 1:1 electrolytes have been determined in (water + ethylammonium nitrate) (EAN) binary at 298.15 K throughout the composition scale. Our theoretical analysis shows that the values of partial molar volumes at infinite dilution of a solute in a binary are linked to those of the partial molar volumes of the components of mixed solvent. This applies to mixtures of molecular solvents as well as (water + ionic liquid) media. The use of the pseudo-lattice theory of Bahe recently supplemented Varela can be used for calculations and to obtain information about the interactions between 1:1 electrolytes as solutes at infinite dilution and their concentrated saline environment. We show that the pseudo-lattice theory allows accurate description of the behaviours of symmetrical tetraalkylammoniums bromide between the infinitely dilute state and concentrations higher than 2 mol center dot L-1. (C) 2007 Elsevier Ltd. All rights reserved.