Biosorption of Zn(II) by orange waste in batch and packed-bed systems

BACKGROUND: This research provides new insights into the biosorption of zinc on a waste product from the orange juice industry. Optimal operating conditions maximizing percentage zinc removal were determined in batch and fixed-bed systems. Biomass was characterized by FTIR spectroscopy and by major cation content in order to better understand the biosorpion mechanism. Zn-loaded orange waste was proposed to be used as an alternative fuel in cement kilns. RESULTS: Sorption capacity was strongly affected by biosorbent dose and solution pH, and was not strongly sensitive to particle size under the experimental conditions studied. Equilibrium data were successfully described by a Langmuir model and sorption kinetic data were adequately modelled with the pseudo-second-order and Elovich rate equation. The biomass was found to possess high sorption capacity (q(max) = 0.664 mmol g(-1)) and biosorption equilibrium was established in less than 3 h. Experimental breakthrough curves were adequately fitted to the Thomas model and the dose-response model, obtaining sorption capacities in continuous assays higher than those found in batch mode. Characterization of the biomass suggested the possible contribution of carboxyl and hydroxyl groups of biomass in Zn2+ biosorption and it also highlighted the important role of light metal ions in a possible ion-exchange mechanism. CONCLUSIONS: Orange waste could be used as an effective and low-cost alternative biosorbent material for zinc removal from aqueous solution. (C) 2010 Society of Chemical Industry