Arsenic adsorption on Ti-pillared montmorillonite

BACKGROUND: Arsenic pollution in drinking water has been found in most countries. Arsenate (As(V)) and arsenite (As(III)) are two major forms of inorganic arsenic species, and the latter is the more toxic. The removal of arsenic ions from water has attracted increased attention, and therefore further understanding and development of techniques for removal of arsenic ions are required. RESULTS: Adsorption of arsenate and arsenite from aqueous solutions using Ti-pillared montmorillonite (Ti-MMT) was investigated as a function of contact time, pH, temperature, coexisting ions, and ionic strength. The adsorption of both arsenate and arsenite were temperature and pH dependent, indicating different adsorption mechanisms. The effect of coexisting ions on the adsorption was also studied and, among the ions investigated, only phosphate had a noticeable influence on the adsorption of arsenate, while the effect of other ions was negligible. A pseudo-second-order chemical reaction model was obtained for both arsenate and arsenite; adsorption isotherms of arsenate and arsenite fitted the Langmuir and Freundlich isotherm models well. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to study the nature of surface elements before and after adsorption. CONCLUSIONS: This work demonstrates that Ti-pillared montmorillonite is an efficient material for the removal of arsenate and arsenite from aqueous solutions. Experimental parameters such as contact time, solution pH, temperature, initial concentration, coexisting ions, and ionic strength have been optimized. (C) 2010 Society of Chemical Industry