期刊
JOURNAL OF CHEMICAL PHYSICS
卷 149, 期 8, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5048838
关键词
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资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/L001593]
- EPSRC [EP/L005913/1] Funding Source: UKRI
This study of the photodissociation of dimethyl sulfide at lambda = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging. Published by AIP Publishing.
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