期刊
JOURNAL OF CHEMICAL PHYSICS
卷 141, 期 7, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.4892582
关键词
-
资金
- Academia Sinica
- Ministry of Science and Technology, Taiwan [NSC100-2113-M-001-008-MY3, NSC102-2113-M-001-012-MY3]
The UV spectrum of CH3CHOO was measured by transient absorption in a flow cell at 295 K. The absolute absorption cross sections of CH3CHOO were measured by laser depletion in a molecular beam to be (1.06 +/- 0.09) x 10(-17) cm(2) molecule-1 at 308 nm and (9.7 +/- 0.6) x 10(-18) cm(2) molecule-1 at 352 nm. After scaling the UV spectrum of CH3CHOO to the absolute cross section at 308 nm, the peak UV cross section is (1.27 +/- 0.11) x 10(-)1(7) cm(2) molecule-1 at 328 nm. Compared to the simplest Criegee intermediate CH2OO, the UV absorption band of CH3CHOO is similar in intensity but blue shifted by 14 nm, resulting in a 20% slower photolysis rate estimated for CH3CHOO in the atmosphere. (C) 2014 AIP Publishing LLC.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据