期刊
JOURNAL OF CHEMICAL PHYSICS
卷 140, 期 17, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.4871877
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资金
- Grants-in-Aid for Scientific Research [25620012] Funding Source: KAKEN
The streaming potentials of liquid beams of aqueous NaCl, NaBr, and NaI solutions are measured using soft X-ray, He(I), and laser multiphoton ionization photoelectron spectroscopy. Gaseous molecules are ionized in the vicinity of liquid beams and the photoelectron energy shifts are measured as a function of the distance between the ionization point and the liquid beam. The streaming potentials change their polarity with concentration of electrolytes, from which the singular points of concentration eliminating the streaming potentials are determined. The streaming currents measured in air also vanish at these concentrations. The electron binding energies of liquid water and I-, Br-, and Cl- anions are revisited and determined more accurately than in previous studies. (C) 2014 AIP Publishing LLC.
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