期刊
JOURNAL OF CHEMICAL PHYSICS
卷 134, 期 11, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3561735
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The Seebeck coefficients of the nonaqueous electrolytes tetrabutylammonium nitrate, tetraoctylphosphonium bromide, and tetradodecylammonium nitrate in 1-octanol, 1-dodecanol, and ethylene-glycol are measured in a temperature range from T = 30 degrees C to T = 45 degrees C. The Seebeck coefficient is generally of the order of a few hundreds of microvolts per Kelvin for aqueous solution of inorganic ions. Here we report huge values of 7 mV/K at 0.1 M concentration for tetrabutylammonium nitrate in 1-dodecanol. These striking results open the question of unexpectedly large kosmotrope or structure making effects of tetraalkylammonium ions on the structure of alcohols. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3561735]
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