期刊
JOURNAL OF CHEMICAL PHYSICS
卷 135, 期 4, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3615940
关键词
approximation theory; colloids; Green's function methods; permittivity; suspensions
资金
- CNPq
- Fapergs
- INCT-FCx
- US-AFOSR [FA9550-09-1-0283]
We introduce a new method for simulating colloidal suspensions with spherical colloidal particles of dielectric constant different from the surrounding medium. The method uses an approximate calculation of the Green function to obtain the ion-ion interaction potential in the presence of a dielectric discontinuity at the surface of the colloidal particle. The method is very accurate and is orders of magnitude faster than the traditional approaches based on series expansions of the interaction potential. (C) 2011 American Institute of Physics. [doi:10.1063/1.3615940]
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