期刊
JOURNAL OF CHEMICAL PHYSICS
卷 134, 期 2, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3528000
关键词
-
资金
- European Research Council
- Austrian Academy of Sciences
- Austrian Science Fund FWF
- Italien Zentrum of the University of Innsbruck
- Beckman Foundation
- CNR
- Austrian Science Fund (FWF) [Y 391, T 463] Funding Source: researchfish
Neutron diffraction experiments on a solution of LiCl in water (R = 40) at ambient conditions and in the supercooled and hyperquenched states are reported and analyzed within the empirical potential structure refinement framework. Evidence for the modifications of the microscopic structure of the solvent in the presence of such a small amount of salt is found at all investigated thermodynamic states. On the other hand, it is evident that the structure of the hyperquenched salty sample is similar to that of pure low density amorphous water, although all the peaks of the radial distribution functions are broader in the present case. Changes upon supercooling or hyperquenching of the ion's hydration shells and contacts are of limited size and evidence for segregation phenomena at these states does not clearly show up, although the presence of water separated contacts between ion of the same sign is intriguing. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3528000]
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据