4.7 Article

Analysis of the continuous-configuration time-dependent self-consistent field method applied to system-bath dynamics

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JOURNAL OF CHEMICAL PHYSICS
卷 132, 期 10, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3351903

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harmonic oscillators; quantum theory; SCF calculations; vibrational states

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  1. Deutsche Forschungsgemeinschaft [Ne873/3-1]

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We have implemented and studied the continuous-configuration time-dependent self-consistent field scheme, a variation of the multiconfiguration time-dependent Hartree method, which aims to get around the latter's exponential scaling problem, especially with regard to system-bath dynamics. We present applications to quantum dissipative dynamics and an analysis of the computational effort. Namely, propagation times within this scheme scale linearly with the number of bath modes.

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