4.7 Article

Derivation of dynamical density functional theory using the projection operator technique

期刊

JOURNAL OF CHEMICAL PHYSICS
卷 131, 期 24, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3266943

关键词

Brownian motion; colloids; density functional theory; diffusion; liquid theory; suspensions

资金

  1. Freiburg Institute for Advanced Studies and BIFI
  2. MICINN [FIS2007-65869-C03-03]

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Density functional theory is a particular case of a general theory of conjugate variables that serves as the basis of the projection operator technique. By using this technique we derive a general dynamical version of density functional theory which involves a generalized diffusion tensor. The diffusion tensor is given by a Green-Kubo expression. For Brownian dynamics of dilute colloidal suspensions, the standard dynamical density functional theory is recovered.

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